Wednesday, November 18, 2009

Direction of Dipoles is represented by an arrow toward negative poles and a cross at the positive pole. the positive dipole is indicated as follows

-I-->
H Cl

the negative region in one polar molecule attracts the positive region in adjacent molecules. the moleules are attracted to each other by opposite sides.
each forces of attraction between polar moleules are known as a dipole- dipole forces

dipole-dipole foreces act at short range only between nearyby molecules.
this explains the high boiling point in molcules with dipole dipole forcesex I-Cl (97 c) but Br-Br (59 c)


a polar molecule can induce a dipole in a non polar molecule by temporarily attracting its electrons
the result is a short range intermolecular force that is weaker than a dipole-dipole force.
this accounts for the oxygen's ability to be dissolved into water
some hydrogen containg compounds have high boiling points. explored by a particularly strong of dipole-dipole force
examples are phosphorous and sulfur
this gives a hydrogen atom a positive charge that is almost half that of a bare proton
the small size of the hydrogen atom allows it come close to an unshared pair in another atom
this forms a hydrogen bond
these are connected with a dotted line
excellent example is water
properties aquired from hydrogen bonding are surface tension, cohesion, solvent, and boiling point is raised
london dispersion theory
even noble gas atoms and non polar molecules can experience weak intermolceular bonding
in any atom or molecule the electrons are in constant motion
thus there exists a possibilty of there being a more positive and negative side which attracts the more negative or positive sides of a different atom or molecule
this is the weakest type of bond
suggested in 1930

20 comments:

  1. im likin the graph Chris, but anyways here is some sample problems on dipoles:

    http://physics.umd.edu/perg/abp/TPProbs/Problems/E/E26.htm

    ReplyDelete
  2. Good website on dipoles

    http://www.newton.dep.anl.gov/askasci/gen01/gen01606.htm

    ReplyDelete
  3. this site is about london dispersion forces

    http://www.chem.purdue.edu/gchelp/liquids/disperse.html

    ReplyDelete
  4. Good site about dipoles http://www.cartage.org.lb/en/themes/Sciences/Chemistry/Miscellenous/Helpfile/LiquidandSolid/LondonDispersion.htmut dipoles:

    ReplyDelete
  5. this is a good website about dipoles

    http://world.std.com/~mmcirvin/bluesky/molecule.html

    ReplyDelete
  6. here's a video on hydrogen bonding. http://www.youtube.com/watch?v=ZlVUXLBJg14

    ReplyDelete
  7. london dispersion forces
    http://www.lrsm.upenn.edu/~frenchrh/dispersion_forces.htm

    ReplyDelete
  8. This page is about intermolecular interactions http://www.science.uwaterloo.ca/~cchieh/cact/c123/intermol.html

    ReplyDelete
  9. http://www.chemguide.co.uk/atoms/bonding/electroneg.html

    ReplyDelete
  10. Great graph. More information on molecular geometry


    http://mysite.verizon.net/kdrews47/molegeo/molegeo.html

    ReplyDelete
  11. Here is a site tha discusses direction of dipoles.
    http://hyperphysics.phy-astr.gsu.edu/hbase/electric/dipole.html

    ReplyDelete
  12. Very helpful site concerning dipoles:

    www.kettering.edu/~drussell/Demos/rad2/mdq.html

    ReplyDelete
  13. here is a good site on hydrogen bonding.

    http://www.elmhurst.edu/~chm/vchembook/161Ahydrogenbond.html

    ReplyDelete
  14. http://www.chem.purdue.edu/gchelp/liquids/disperse.html

    Good website on London Dispersion Forces

    ReplyDelete
  15. A website to help explain London Dispersion Forces

    http://www.chem.purdue.edu/gchelp/liquids/disperse.html

    ReplyDelete
  16. http://www.youtube.com/watch?v=lkl5cbfqFRM

    Quick video that discusses Hydrogen bonding

    ReplyDelete
  17. This website explains upon intermolecular forces.
    http://thestephenation.blogspot.com/2009/09/london-dispersion-forces.html

    ReplyDelete
  18. Here's a video on molecular dipoles

    http://www.youtube.com/watch?v=c5VRfMuFxo4

    ReplyDelete
  19. http://www.physicsforums.com/showthread.php?t=154961

    helps with london dispersion forces

    ReplyDelete
  20. http://users.rcn.com/jkimball.ma.ultranet/BiologyPages/H/HydrogenBonds.html
    website about hydrogen bonding

    ReplyDelete